2-[(Anilino)(2-nitrophenyl)methyl]cyclohexanone
نویسندگان
چکیده
In the title compound, C(19)H(20)N(2)O(3), the cyclo-hexa-none ring adopts a chair conformation with the amino-methyl group is positioned equatorially. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds.
منابع مشابه
2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone
In the mol-ecule of the title compound, C(23)H(29)NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)...
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In the title compound, C(17)H(19)NO(8) [systematic name = dimethyl 4-hydroxy-4-methyl-2-(3-nitrophenyl)-6-oxocyclohexane-1,3-dicarboxylate], the cyclo-hexa-none ring exhibits a chair conformation. The meth-oxy-carbonyl groups are oriented in opposite directions with respect to the cyclo-hexa-none ring. In the crystal, O-H⋯O hydrogen bonds links the mol-ecules into chains running parallel to the...
متن کاملN-[(2-Hydroxy-5-methoxyphenyl)(3-nitrophenyl)methyl]acetamide
In the title compound, C(16)H(16)N(2)O(5), the meth-oxy group is disordered with site occupancies of 0.20 (3) and 0.80 (3). The dihedral angle between the two aromatic rings is 73.7 (2)°. The crystal structure is characterized by intermolecular N-H⋯O, O-H⋯O, C-H⋯O and C-H⋯π hydrogen bonds.
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The title compound, C(23)H(24)N(2)O(3), was synthesized from naphthalen-2-ol, 3-nitro-benzaldehyde and 3-methyl-piperidine. The dihedral angles between the naphthalene system and the nitro-benzene and methyl-piperidine rings are 78.53 (13) and 64.14 (15)°, respectively. The mol-ecular conformation is stabilized by a strong intra-molecular O-H⋯N hydrogen bond.
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